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ARSENIC
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Atomic Number:33
Atomic Symbol:As
Atomic Weight:74.9216
Electron Configuration:[Ar]4s23d104p3
Total Isotopes44
Total Isomers11
Radioactive Isotopes32
Stable Isotopes1
X-Ray Energies
10.53
11.73
LL1.12
1.28
Mz

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History

(L. arsenicum, Gr. arsenikon, yellow orpiment, identified with arenikos, male, from the belief that metals were different sexes; Arabic, Az-zernikh, the orpiment from Persian zerni-zar, gold) Elemental arsenic occurs in two solid modifications: yellow, and gray or metallic, with specific gravities of 1.97, and 5.73, respectively. It is believed that Albertus Magnus obtained the element in 1250 A.D. In 1649 Schroeder published two methods of preparing the element. Mispickel, arsenopyrite, (FeSAs) is the most common mineral from which, on heating, the arsenic sublimes leaving ferrous sulfide.

Properties

Element DisplaysThe element is a steel gray, very brittle, crystalline, semimetallic solid; it tarnishes in air, and when heated is rapidly oxidized to arsenous oxide with the odor of garlic. Arsenic and its compounds are poisonous.

Uses

Arsenic is used in bronzing, pyrotechny, and for hardening and improving the sphericity of shot. The most important compounds are white arsenic, the sulfide, Paris green, calcium arsenate, and lead arsenate; the last three have been used as agricultural insecticides and poisons. Marsh's test makes use of the formation and ready decomposition of arsine. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light.


Sources: Los Alamos National Laboratory; CRC Handbook of Chemistry and Physics; American Chemical Society
Element image from www.element-collection.com used with permission
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